It is possible to use tools of Divination, Mantic and Tarot are suitable, if you know how to use them. However, to use Tarot you must be somewhat Enlightened, for we can simply misinterpret the Messages of the Cards. Tarot is a Powerful Tool, its Symbolism and application goes beyond just Divination as such, and here you need to really understand the essence of the Tool more Deeply, so that your Consciousness and your Soul can perceive more information. But with the help of Tarot you can find out a lot of things, both about love, and about enemies, and about money investments, and about dangers in the future. But Tarot is more difficult to Master (because of its depth) than Mantic or Pendulum.
If you want to identify a lie in the moment, then indeed Psychic Abilities, if Developed, can help very well. If it is someone very close to you, you have a Connection at the Chakras and Aura Level, including even at the Third Eye Level. So it is not a joke that you have a Mental Connection. If you have Developed a certain Astral Sensitivity, then through the Third Eye you can pick up this Information, as if «Projected» into it. This is one of the types of Mental Projection (not Astral Projection). Close people a priori have a Deeper Mental Connection, even if they don't realize it.
When it comes to unknown people, you will most likely need a Powerful Psychic. At an Advanced Level a person is able to pick up very «subtle» Energy like Emotions, because Emotions are also a form of Energy, and it takes Experience and the necessary Psychic Openness to begin to discern and interpret it correctly. When a person lies, you will be able to perceive it literally on the Level of his Feelings.
There are natural Empaths, and Empathy is not just a Perceptual mechanism, but a Psychic Tool. In most Empaths it works chaotically, they Feel the surrounding Energy very acutely and it is difficult for them to control it, especially in megacities where a lot of Negativity is concentrated and people spew it out and Empaths Absorb it. When Empathy is under your control, you can literally Filter and Absorb all the Energy Information from other people's Emotions very accurately: sadness, joy, love, hate, jealousy and, of course, lies.
Another Psychic Tool is, of course, Intuition. As with Empathy, it is completely random in most people. It is a trainable Skill. At the most Advanced Level, you won't even need the Tools of Divination, as Intuition will be extremely Powerfully Developed. This is indeed true, but it is more of a Superhuman/Hero (according to our classification) or even Demonic Level of Spiritual Evolution. When you literally have the Ability for some form of Divination/Vision. Of course, the person will be open like a book to you, you will see right through them, especially whether they are lying to you or telling you the truth. Which you will be able to determine instantly.
Perhaps Telepathy should also be mentioned here, which may in fact include all of the previous points. Telepathy can be called an Ability for very Advanced people, for real Adepts who have Mastered it. It is, of course, an Advanced Method, we are not talking about easier Techniques of application. At the Higher Levels Telepathy will allow you not only to determine thoughts and Feelings, but also to Influence these thoughts and Feelings, even to correct them, both for the worse and for the better. This is very difficult. For example, we can be Blessed by the Gods in this way. They literally Charge us with this or that Knowledge, which was previously unavailable for us. And in this way you could finally believe in Satan/Zeus when you were in a very difficult confusion. The Appearance of a Projection of a Demon, by the way, can have the same Effect, one can literally shudder before it, because of the incredible amount of Bioelectricity felt, you can't literally lie to the Demon, because its Essence Influences you, turning you inside out (in a positive way).
You can also Program your Aura or make a Magical Program to stop a particular person from lying to you. Here it is also important to work on Affirmations. It can be a Thoughtform, Elemental or Golem, which you «attach» to the Soul of a person, so that it collects the necessary Information and sends it to you. A Thoughtform can be «attached» to the Lunar Chakra, for example, as it is closely intertwined with the brain and can Influence and correct Behavioral and Mental Mechanisms of a person. However, such a Method also requires Experience. Or, as an alternative variant, you can Program a person on the necessary Program, having compelled the Mind of the person to tell you the truth about something. This should be done at the time when a person is sleeping. It is at this time that Brainwaves and their Frequency slow down, and the Consciousness is vulnerable to interference. Then a Program can be sent to make it effective. It will take several such Sessions, depending on the Powers of your Soul. For example, our GDs and other Demons may visit us in our dreams, when we are most Emotionally disturbed, to have some intense Interaction with us or to answer a question. In a dream a person is vulnerable to External Influence, and this is taken advantage of by Parasitic Entities, which are Enemy Entities that can make Astral Attacks during sleep to feed on Fear Energy, suck Energy, etc. That is, when a person sleeps a person can have extremely intense Feelings, and then under the impression of them even exhibit the desired behavior, because the brain has internalized it.
If you have Mastered the Art of Hypnosis, you can use Hypnotic Techniques to get a person not to hide lies. This is even somewhat similar to the Programming of a person's Consciousness when he or she is asleep, which I mentioned above, but Hypnosis allows you to do this during the daytime as well, if the person is open and ready for this process beforehand, because you will then put him or her into a state bordering on sleep. Advanced Hypnosis Techniques, including the so-called «Dark Hypnosis», allow you to literally make a person do exactly what you need, absolutely corresponding to your expectations, to bind his Will. But this is not Ethical, this is what many evil people do, using people as their puppets and sex slaves, so approach it with Nobility and Honor, Stay Human. Above I only described the Potential of the Technique itself, its Effectiveness of application. Similarly, very Advanced Hypnosis allows through the Third Eye to Program the Mind.
You can certainly use the Logical Side of the brain (Pingala), deductive analysis, NLP, the technique of reading Body Language and other Methods (which, for example, practiced in Special Agencies), but it is unlikely to be as effective as identification with the help of Psychic Powers, because this «Left-Hemispheric» Method does not have accuracy and a priori does not always give a guaranteed result. I have studied all this myself and even by my Experience I can confirm it with all responsibility. By the way, the Special Agencies know this, that's why they have employees with Psychic Abilities, which they use in interrogations, for example.